The Invention of Paper

 

The Birth of Papermaking

AD 105 is often cited as the year in which papermaking was invented. In that year, historical records show that the invention of paper was reported to the Chinese Emperor by Ts'ai Lun, an official of the Imperial Court. Recent archaeological investigations, however, place the actual invention of papermaking some 200 years earlier. Ancient paper pieces from the Xuanquanzhi ruins of Dunhuang in China's northwest Gansu province apparently were made during the period of Emperor Wu who reigned between 140 BC and 86 BC. Whether or not Ts'ai Lun was the actual inventor of paper, he deserves the place of honor he has been given in Chinese history for his role in developing a material that revolutionized his country.

Early Papermaking in China

Papermaking in China Early Chinese paper appears to have been made by from a suspension of hemp waste in water, washed, soaked, and beaten to a pulp with a wooden mallet. A paper mold, probably a sieve of coarsely woven cloth stretched in a four-sided bamboo frame, was used to dip up the fiber slurry from the vat and hold it for drying. Eventually, tree bark, bamboo, and other plant fibers were used in addition to hemp.

The first real advance in papermaking came with the development of a smooth material for the mold covering, which made it possible for the papermaker to free the newly formed sheet and reuse the mold immediately. This covering was made from thin strips of rounded bamboo stitched or laced together with silk, flax, or animal hairs. Other Chinese improvements in papermaking include the use of starch as a sizing material and the use of a yellow dye which doubled as an insect repellent for manuscript paper.

Papermaking Spreads Throughout Asia

From China, papermaking moved to Korea, where production of paper began as early as the 6th century AD. Pulp was prepared from the fibers of hemp, rattan, mulberry, bamboo, rice straw, and seaweed. According to tradition, a Korean monk named Don-cho brought papermaking to Japan by sharing his knowledge at the Imperial Palace in approximately AD 610, sixty years after Buddhism was introduced in Japan. The Japanese first used paper only for official records and documentation, but with the rise of Buddhism, demand for paper grew rapidly.

Taught by Chinese papermakers, Tibetans began to make their own paper as a replacement for their traditional writing materials. The shape of Tibetan paper books still reflects the long, narrow format of the original palm-leaf books. Chinese papermakers also spread their craft into Central Asia and Persia, from which it was later introduced into India by traders. The first recorded use of paper in Samarkand dates from a battle in Turkestan, where skilled Chinese artisans were taken prisoner and forced to make paper for their captors.

The Spread of Papermaking in Europe

From Samarkand, papermaking spread to Baghdad in the 8th century AD and into Damascus, Egypt, and Morocco by the 10th century. Many Chinese materials were not available to Middle Eastern papermakers, who instead used flax and other substitute fibers, as well as a human-powered triphammer to prepare the pulp.

It took nearly 500 years for papermaking to reach Europe from Samarkand. Although the export of paper from the Middle East to Byzantium and other parts of Europe began in the 10th and 11th centuries, the craft was apparently not established in Spain and Italy until the 12th century. Early paper was at first disfavored by the Christian world as a manifestation of Moslem culture, and a 1221 decree from Holy Roman Emperor Frederick II declared all official documents written on paper to be invalid. (The interests of wealthy European landowners in sheep and cattle for parchment and vellum may also have exerted some influence.) The rise of the printing press in the mid 1400's, however, soon changed European attitudes toward paper.

The Papermaker

This life-size statue, which stands in the center of the Paper Museum, is an adaptation of an illustration entitled "The Papermaker," which is believed to have first appeared in 1698 in the Book of Trades by Christopher Weigel. It next appeared in 1717 in the Book of Trades by Abraham van St. Clara, a copy of which is held by the Museum. The reproduction on which the statue is based appears on page 43 of Dard Hunter's book Papermaking Through Eighteen Centuries (New York: William Edwin Rudge, 1930), which is also on display in the Museum. In all its forms, "The Papermaker" is an excellent introduction to the craft of papermaking in pre-industrial Europe.

The Papermaker

The Process of Papermaking

Although the craftsman depicted in our statue would hardly recognize the equipment of a modern paper mill, the procedures he used to make paper were not that different from the processes of today. Preparing the stock, forming the paper web, drying the sheet, and applying coatings and additives were all as much a part of his work as they are of ours. Although many improvements in technology were made after the introduction of papermaking to Europe, the following description will give some impression of the operations which made up the papermaker's craft.

Raw Materials for Paper

The material of choice for the European papermaker was cotton or linen fiber from rags. The rags were sorted, cleaned, and heated in a solution of alkali, at first in an open vat and later under steam pressure. After draining and seasoning, the rags were then washed and macerated to a pulp, which was then bleached to remove the final traces of dyes and the residual darkening from the cooking process.

Paper Molds

To form a sheet of paper, the papermaker dipped a paper mold into the vat of stock and lifted it out horizontally, trapping the fibers against the screen of the mold. Paper molds were made by hand from parallel lengths of wire laced together together with fine wire or thread ("laid" molds) or from woven wire mesh ("wove" molds).

Drying the Sheet

After forming, the sheet was removed ("couched") from the mold and placed on felts or woolen cloth for pressing. A stack of paper sheets and felts, called a "post," was placed in a large wooden screw press, and all the workers in the mill were summoned to tighten the press by pushing or pulling a long wooden lever. An average 2-foot post might be reduced to 6 or 8 inches in this way.

After pressing, the sheets were strong enough to be lifted from the felts and hung to dry, usually in groups of four or five known as "spurs" to prevent wrinkling and curling. Drying was usually carried out in the highest level of the mill, away from soot and dust.

Sizing and Finishing

To make the paper less absorbent, the dried sheet was dipped in animal gelatin or glue. Such sizing was more important for writing papers than for printing stock, since printing inks were thicker and did not soak into the paper so easily. The first method for smoothing the sheet was simply to burnish each sheet by hand with a glossy stone; a water-powered hammer smoother was developed in the early 17th century.

Dard Hunter

 

Young Dard Hunter

Dard Hunter was born on November 29, 1883 into an Ohio family with a long tradition of printing and publishing. His given name was William Joseph. The origin of the nickname "Dard" remains unknown. Seeking a career in art, he joined Elbert Hubbard's Roycrofters in East Aurora, New York, in 1904. As a leading proponent of America's Arts and Crafts Movement, Hubbard encouraged Hunter to develop his artistic talents in many media, including graphic design, stained glass, and metalwork. Hunter is now considered one of the movement's greatest artists.

Dard Hunter's Introduction to Papermaking

In 1911, Dard Hunter visited London, where he became fascinated with early European papermaking and printing. He returned to America to set up a shop in Marlborough-on-Hudson, New York. In printing his first book in 1915, The Etching of Figures by William Bradley, Hunter continued to practice the creed of the Arts and Crafts Movement, whose proponents believed that a hand-crafted object was inherently more desirable, beautiful, serviceable, and worthy of human endeavor than anything made by a machine.

Dard Hunter, Paper Historian

After moving to Chillicothe, Ohio, in 1919, Hunter decided to devote his life to researching, collecting, writing, and publishing the world's history of hand papermaking and printing. Over the next ten years, he published three limited-edition books at his Mountain House Press. Their titles were Old Papermaking (1923), Literature of Papermaking (1925), and Primitive Papermaking (1927). In 1928, he started up a second paper mill in Lime Rock, Connecticut. Although a commercial failure, Hunter's Lime Rock Mill nevertheless became the inspiration for many of the successful handmade paper mills in the United States today.

The Dard Hunter Paper Museum

Although Dard Hunter had originally intended to establish a museum in the Lime Rock mill for his large collection of books and artifacts, the Dard Hunter Paper Museum first opened in 1939 at the Massachusetts Institute of Technology in Cambridge. In the Museum's brochure, Hunter stated that the Paper Museum was established "...with the hope of stimulating interest in the ancient craft of papermaking and promoting understanding of present-day paper and its relation to the graphic arts." In 1954, the Museum was acquired by The Institute of Paper Chemistry (now Renewable Bioproducts Institute), which was then located in Appleton, Wisconsin. Dard Hunter was named the Museum's Honorary Curator.

Dard Hunter's Legacy

By the time of his death on February 20, 1966, Dard Hunter was responsible for a renaissance in hand papermaking and printing. From 1923 to 1950, his Mountain Home Press produced eight limited-edition books that stand as testaments to his devotion and perseverance. Today, most of the historians and artisans interested in papermaking and printing were directly inspired by Hunter. To the public, the Dard Hunter Collection in the Robert C. Williams Paper Museum represents an invaluable and irreplaceable legacy, because most of the world's cultural history is borne by this seemingly fragile and insignificant material - paper.

Papermaking Moves to the United States

The First Mill in America

The first paper mill in America was established in 1690 by William Rittenhouse near Germantown, Pennsylvania. In 1688, Rittenhouse left Holland, where he had been an apprentice papermaker, and settled in Philadelphia, near the print shop of William Bradford. The Rittenhouse mill remained the only mill in America until 1710, when William DeWees, brother-in-law to William Rittenhouse's son Nicholas, established his own mill.

Most early mills in the American colonies were started by transplanted papermakers, like Rittenhouse, who modeled their operations on European mills of the day. These mills had to be located near populated areas that could provide a reliable supply of rags, the main raw material at that time. A generous supply of fresh water was also a requirement, both for washing the fibers and turning the mill machinery.

Paper for Printing in the Colonies

Many colonial paper mills, such as the Rittenhouse mill, were also located near print shops. Even before they had a reliable supply of paper, however, the colonies had begun to publish newspapers. The first newspaper in the colonies was the Boston News Letter, which appeared in 1705; the second was the Boston Gazette, first published in 1719. The third, also dating from 1719, was Bradford's Mercury, which was published by Andrew Bradford, the son of printer William Bradford. To supply paper for the New York Gazette, William Bradford started a paper mill in New Jersey around 1726.

With the Stamp Act of 1765, Great Britain tried to raise revenue by taxing all colonial commercial and legal papers, newspapers, and pamphlets. Because of the export trade in paper, Britain attempted to restrict papermaking in the colonies, but due to the shortage of paper in America, these restrictions were not rigorously applied. It was only when colonial printers began to express their discontent with British rule that Britain really tried to control the production of paper.

Mold Making in the Colonies

Although some of the machinery used in early mills was imported from Europe, much of the machinery was constructed in the colonies. A high degree of craftsmanship was also required to create a paper mold; however, the lack of skilled mold makers in the colonies meant that many paper molds were imported from England.

Nathan Sellers of Pennsylvania was a skilled wire drawer who applied his craft to the manufacture of paper molds. Between 1776 and 1820, he supplied the molds for hundreds of American papermakers. This ability was so rare that, when Sellers joined the American army in the fall of 1776, he was soon discharged by a special resolution of the Contiental Congress, which sent him home to create the molds that were so desparately needed to make the paper used for powder wrappers and written orders during the Revolutionary War.

Paper Mill Construction After the Revolutionary War

Ream Wrapper By 1810, there were some 185 paper mills in the new United States. Ream wrappers were used to identify a mill's products, and they were often printed with a picture of the mill. As existing mills expanded and new mills began production, rags for making paper became scarce, and the search for more plentiful raw materials began.

American papermakers began experimenting with alternative raw materials as early as the 1790's, and many mills tested local sources of fiber as substitutes for rag pulp, including tree bark, bagasse (sugarcane waste), straw, and cornstalks. Wood pulp became a viable option thanks to the work of Mathias Koops in England and the increasing availability of mechanical wood grinders. The first US newspaper to be printed on paper made from ground wood pulp was the edition of the Boston Weekly Journal that appeared on January 14, 1863.

The Modern Paper Mill

The modern paper mill is a highly complex industrial facility. Although the principles of papermaking have not fundamentally changed for many years, a papermaker from Imperial China or pre-industrial Europe would be hard pressed to recognize his craft amongst all the equipment of a modern mill. To explore how a present-day paper mill operates, let's follow the path of an individual wood fiber from its arrival at the mill to its departure.

Delivery and Preparation

Most of the mill's raw material arrives by truck or rail in the form of logs. The logs are soaked in water and tumbled in slatted metal drums to remove the bark. The debarked logs are then fed into a chipper, a device with a rotating steel blade that cuts the wood into pieces about 1/8" thick and 1/2" square. (In some cases, the wood may have been chipped, bark and all, when it was harvested.) The wood chips are stored in a pile outside the mill; as new chips are added to the top of the pile, others are withdrawn fro the bottom and carried by conveyor to the digester.

Pulping

Digesting is the process of removing lignin and other components of the wood from the cellulose fibers which will be used to make paper. Lignin is the "glue" which holds the wood together; it rapidly decomposes and discolors paper if it is left in the pulp (as in newsprint, which is usually made from groundwood pulp with little or no chemical treatment). Since this is a "kraft" mill, the lignin is removed by the action of sodium hydroxide ("caustic soda") and sodium sulfate under heat and pressure. The chips are fed into the top of a digester and mixed with the cooking chemicals, which are called "white liquor" at this point. As the chips and liquor move down through the digester, the lignin and other components are dissolved, and the cellulose fibers are released as pulp. At the bottom of the digester, the pulp is rinsed, and the spent chemicals (now known as "black liquor") are separated and recycled.

Bleaching and Refining

At this point, the "brownstock" pulp is free of lignin, but is too dark to use for most grades of paper. The next step is therefore to bleach the pulp by treating it with chlorine, chlorine dioxide, ozone, peroxide, or any of several other treatments. A typical mill uses multiple stages of bleaching, often with different treatments in each step, to produce a bright white pulp. Chlorine bleaching generally provides the best performance with the least damage to the fibers, but concerns about dioxins and other byproducts have led the industry to move towards more environmentally friendly alternatives.

At this point, the individual cellulose fibers are still fairly hollow and stiff, so they must be broken down somewhat to help them stick to one another in the paper web. This is accomplished by "beating" the pulp in the refiners, vessels with a series of rotating serrated metal disks. The pulp will be beaten for various lengths of time depending on its origin and the type of paper product that will be made from it. At the end of the process, the fibers will be flattened and frayed, ready to bond together in a sheet of paper.

Forming the Sheet

Once the pulp has been bleached and refined, it is rinsed and diluted with water, and fillers such as clay or talc may be added. This "furnish", containing 99% water or more, is pumped into the headbox of the paper machine. From the headbox, the furnish is dispensed through a long, narrow "slice" onto the "wire", a moving continuous belt of wire or plastic mesh. As it travels down the wire, much of the water drains away or is pulled away by suction from underneath. The cellulose fibers, trapped on the wire as the water drains away, adhere to one another to form the paper web. From the wire, the newly formed sheet of paper is transferred onto a cloth belt (or "felt") in the press section, where rollers squeeze out much of the remaining water.

Coating, Drying, and Calendering

After leaving the press section, the sheet encounters the drying cylinders. These are large hollow metal cylinders, heated internally with steam, which dry the paper as it passes over them. The sheet will be wound up and down over many cylinders in the drying process. Between dryer sections, the paper may be coated with pigments, latex mixtures, or many other substances to give it a higher gloss or to impart some other desirable characteristic. After another round of drying, the paper sheet is passed through a series of polished, close-stacked metal rollers known as a "calender" where it is pressed smooth. Finally, the sheet is collected on a take-up roll and removed from the paper machine. From the headbox, it may have traveled half a mile or more in less than a minute.

Cutting and Packaging

In many cases, the new paper roll is simply rewound on a new core, inspected, and shipped directly to the customer. Other paper grades, however, may be further smoothed by passing them through a "supercalender" where the sheet is polished by passing between steel and hard cotton rollers (much like ironing fabric), or they may be embossed with a decorative pattern. The paper may also be cut into sheets at the mill, often by automatic equipment which accepts a roll of paper at one end and delivers packages of cut sheets at the other, already boxed and wrapped for shipping.

Papermaking today is one of North America's most capital-intensive industries, devoting large sums of money to the development and construction of newer and more efficient equipment and processes. Although we ourselves might not recognize the paper mills of three hundred years from now, the same basic processes will almost certainly be in use to produce a product that will still be in demand far into the future.

 

Watermarks

European papermakers were the first to use watermarks. An offshoot of the guild system, the watermark served as a means of identifying the paper with the members of the trade organization who manufactured it. Just as with trademarks stamped into silver or firearms, the watermark indicated that the paper was the product of a trained artisan's labors.

Wire Watermarks

Wire watermarks are formed by attaching a wire pattern to the mesh of a paper mold. When the paper slurry is drained of its water, the layer of residual fibers over the raised wire pattern is thinner than the rest of the sheet. When pressed and dried, these thinner areas result in patterns that only show clearly when held up to the light.

Light and Shade Watermarks

Light and shade watermarks are formed from relief sculptures impressed into the woven wire fabric of the paper mold. The image to be duplicated is first carved in wax, and the wax model is used to cast male and female plates. Heated wire fabric is placed between the two plates, which are pressed together; this causes the wire fabric to conform to the shape of the image. Paper cast on this type of mold is thinner in the raised areas of the image and thicker in the recessed areas, which creates a light and shade design.

Queen Elizabeth II watermark Madonna and Child watermark

The watermark on the left is a portrait of Queen Elizabeth II from the time of her coronation in 1953. On the right is a Madonna and Child watermark by Pietro Miliani Fabriano. You can click on either of these images to retrieve a larger version in JPEG format.

Dandy Rolls

The invention of the paper machine created a need for a way to make watermarks on the continuous roll of paper. The "Dandy-Roll," probably invented around 1825, was conceived to make an impression like a watermark by rolling over the damp paper just coming off the wire cloth of the paper machine. Dandy rolls can be of "laid" or "wove" design and can contain simple or intricate watermarking designs.

The Advent of the Paper Machine

Nicholas-Louis Robert

In 1798, the Frenchman Nicholas-Louis Robert (1761-1828) invented a prototype of a machine on which paper was formed on a continuous sheet of wire cloth. The invention was patented on January 18, 1799. After Robert, a sargeant-major, left the French army, he had gone to work as a proofreader for the noted printer Pierre-Francois Didot, and was soon placed in charge of the accounting department at son St. Leger Didot's mill in Essones, France. While there, Robert had conceived the idea of a machine to produce a continuous roll of paper to fill the urgent need for banknotes after the French Revolution.

St. Leger Didot encouraged Robert to use the mill's workshop and materials in the development of the paper machine. After five years of work, Robert completed the design and sold his patent rights to St. Leger Didot for the sum of 27,400 francs. Financial difficulties at the mill, however, prevented Didot from paying Robert for the patent, and although Robert eventually recovered ownership, he was never able to realize any money for his invention.

The Fourdriniers

Didot took the models created by Robert to his English brother-in-law, John Gamble, who secured English patent 2487 for an improved version of the machine in April 1801. The improved machine came to the attention of brothers Henry and Sealy Fourdrinier, who engaged engineer Bryan Donkin and built a new and further improved machine in 1807. Although the Fourdriniers invested up to 60,000 pounds on the development of this machine, they received no royalties because of an error in their patent. They did gain some recognition, however, as most modern paper machines are referred to as "fourdrinier" machines. Bryan Donkin was the only person who gained financial security from his work on the paper machine; by 1851, he had designed a total of 191 machines, including 83 for British mills, 105 for Europe, one for India, and two for the United States.

The First Paper Machines in America

The first fourdrinier machine in the US was imported from England and erected in Saugerties, New York, in 1827. The second was built in Connecticut by mechanic George Spafford. He and his partner, James Phelps, completed the first American-built fourdrinier in May 1829 and sold it to Amos Hubbard at a cost of $2,426.

In 1809, a cylinder-type paper machine was introduced by John Dickinson of Hertfordshire, England. Amid great secrecy, Thomas Gilpin built the first cylinder machine in America at Brandywine Creek, Pennsylvania. It produced a sheet 30 feet wide at a rate of 60 feet per minute.

Paper in Our Lives

Each person in the United States consumes approximately 675 pounds of paper a year. Where does it all go? You might be surprised at some of the answers...

Printing, Media, and Entertainment

We read over 350 million magazines, 2 billion books, and 24 billion newspapers a year - all printed on paper. Our children play with paper dolls, paper masks, paper board games, and paper kites. Your ticket to a movie is made out of paper, and so are the containers and carry-out trays for your popcorn and drinks. Even the batteries in your TV remote control contain paper, and so does your television itself.

At Work and School

Most of us expect to find paper in schools and businesses; our desks are usually covered with it. Thanks to computers, which were once expected to make ours a paperless society, we now generate even more paper than ever before. And our money, checks, stock certificates, deeds of ownership, birth certificates and marriage licenses, all the documents which govern our lives, are made out of paper.

Packaging

How would you ship light bulbs, water glasses, or your new microwave oven without the corrugated containers that protect them? The largest category of paper products today is the one we take most for granted - paperboard. Corrugated board is used to ship 95% of all manufactured goods (even paper itself!) and is much lighter and more recyclable than the wooden crates of yesteryear.

Frozen orange juice - the cornerstone of the American breakfast - would be less convenient without the composite foil-lined can. And where would your breakfast be without cereal boxes, coffee filters, or egg and milk cartons? Even sausage casings contain paper! In some cases your coffee cake is baked, sold, reheated, and served in its original paperboard box.

Construction

We use paper to build our homes. Sometimes it serves as a structural or decorative component, as in laminated kitchen counter tops, insulation, gypsum board, acoustical board, wallpaper, flooring, and shingles. Paper is the backing material for masking tape, sandpaper, and electrical cable wrap. And when shelter is needed in an emergency, we can make a whole house out of paperboard.

Paper - the Essential Material

As you can see, paper has evolved over the years from just a writing surface to a material that touches nearly every aspect of our lives. Although we frequently take it for granted, it's hard to imagine what our lives might be like without it.

Recycling in the Paper Industry

Have you ever wondered what happens to a piece of paper when you recycle it? The paper industry is responsible for most of the recycling now taking place in the United States. And 1993 was the first year in history in which more paper was recycled than was buried in landfills. But recycling is not as simple as it may seem...

Paper can be recycled only 5 to 8 times before the fibers in the paper become too short and weak to be reused. Old newspapers are commonly used to make tissue and cardboard, while magazines are often recycled into newsprint. Interestingly, the clay originally added to the paper to make it glossy will help to separate the ink from the paper during recycling.

How Paper is Recycled

First, the waste paper must be collected. One of the most expensive parts of recycling is the collection, sorting, baling, and transportation of waste paper. You can help by presorting your household waste, by separating newspapers, for example, from magazines. It is also important to keep the paper out of rain and sunlight, because exposure to the elements makes it harder to remove the ink from the paper.

The next step in the recycling process is repulping. The bales of sorted waste paper are soaked in large vats, where they disintegrate into fibers. Chemicals are added at this point so that, when ink particles start to separate from the paper, they can't reattach themselves to the pulp.

To remove the ink, the pulp is fed into a deinking system. First, a series of increasingly fine screens remove extraneous material (known as "trash"), coatings and additives, and extremely small contaminants such as fillers and loose ink particles. The screened pulp is sent through several cleaning stages, where heat, chemicals, and mechanical action may be used to loosen ink particles. Finally, the pulp mixture enters a flotation device, where calcium soap and other chemicals are added. Air bubbles in the mixture float the remaining ink to the surface, where it is skimmed away.

The deinked pulp is now sent to the stock preparation area, where it is treated and loaded into the headbox of a paper machine. From this point, the pulp is treated just the same as if it had been freshly made from wood chips rather than recycled.

At the end of the recycling process, a new paper product has been produced from material that might otherwise have been dumped in a landfill. Recycling is an important way for consumers and papermakers to work together for a cleaner environment.